Articles
Synthesis and Catalysis

[3+2] Cycloaddition

Rate Accelerations of 1,3-dipolar Cycloaddition Reactions in Ionic LiquidsTetrahedron Lett.2000, 41, 735. 在離子液體中進行[3+2] Cycloaddition。
[4+2] Cycloaddition
[4+2] Cycloaddition of Ortho-quinone Methides Promoted by Ionic Liquids: an Efficient and Mild Protocol for the Synthesis of TetrahydropyranobenzopyransAdv. Synth. Catal. 2004, 346, 607. 在離子液體中進行[4+2] Cycloaddition合成Tetrahydropyranobenzopyrans。
Acetalization
Application of Functional Ionic Liquids Possessing Two Adjacent Acid Sites for Acetalization of AldehydesJ. Org. Chem. 2004, 69, 3582. 利用修飾過帶酸性的離子液體進行Acetalization。
Aldol Reaction
Direct Catalytic Asymmetric Cross-aldol Reactions in Ionic Liquid Media Tetrahedron Lett.2004, 45, 3949. 以proline在離子液體中催化不對稱Aldol Reaction。
Supported Ionic Liquids. New Recyclable Materials for the L-Proline-Catalyzed Aldol ReactionAdv. Synth. Catal. 2006, 348, 82.將離子液體修飾在silica gel上利用L-Proline催化Aldol Reaction。
Asymmetric Aminohalogenation
Ionic Liquid Media Resulted in the First Asymmetric Aminohalogenation Reaction of AlkenesOrg. Lett. 2004, 6, 4881.這個例子中離子液體可以進行傳統溶劑沒反應的Asymmetric Aminohalogenation。
Asymmetric Diels-Alder Reaction
Asymmetric Diels-Alder Reactions in Ionic LiquidsTetrahedron Lett.2003, 44, 6465. 離子液體中的Asymmetric Diels-Alder Reaction。
Recycling Chiral Imidazolidin-4-one Catalyst for Asymmetric Diels-alder Reactions: Screening of Various Ionic LiquidsAdv. Synth. Catal. 2004, 346, 49. 在離子液體中以imidazolidin-4-one催化Asymmetric Diels-Alder Reaction。
Asymmetric Michael Addition
An Ionic Liquid Influenced L-proline Catalysed Asymmetric Michael Addition of Ketones to NitrostyreneJournal of Molecular Catalysis A: Chemical 2005, 235, 267. 在離子液體中加入L-proline催化Asymmetric Michael Addition。
Aza-Michael Reaction
Cu(acac)2 Immobilized in Ionic Liquids: A Recoverable and Reusable Catalytic System for Aza-michael ReactionsAdv. Synth. Catal.2005, 347, 763. 在離子液體中以Cu催化Aza-Michael Reaction。
Biocatalysis
Ionic Liquid-Coated Enzyme for Biocatalysis in Organic SolventJ. Org. Chem. 2002, 67, 6845. 酵素在離子液體中可以回收重複使用活性不減。
Baylis-Hillman Reaction
Baylis-hillman Reaction in [bdmim][PF6] Ionic Liquid Tetrahedron Lett. 2004, 45, 4673. 在離子液體中進行Baylis-Hillman reaction。
  The DABCO-catalysed Baylis-hillman Reactions in the Chloroaluminate Room Temperature Ionic Liquids: Rate Promoting and Recyclable MediaJournal of Molecular Catalysis A: Chemical 2004, 211, 43. 以DABCO催化及含AlCl3之離子液體進行Baylis-Hillman reaction。
Copper Catalyzed Cross-Coupling
Bipyridinium Ionic Liquid-Promoted Cross-Coupling Reactions between Perfluoroalkyl or Pentafluorophenyl Halides and Aryl IodidesOrg. Lett. 2005, 7, 1963. 以Bipyridinium離子液體進行銅催化Cross-Coupling。
Claisen Condensation & Knoevenagel Condensation
Assessment of the Suitability of Imidazolium Ionic Liquids as Reaction Medium for Base-catalysed Reactions Case of Knoevenagel and Claisen–schmidt ReactionsJournal of Molecular Catalysis A: Chemical2004, 214, 137. 在離子液體中以鹼催化進行Claisen Condensation & Knoevenagel Condensation。
Cyclization
A Novel Reaction in Ionic Liquids: Selective Cyclization of 1-dodecene to Cyclododecane Under Moderate PressureTetrahedron Lett.2003, 44, 2191. 在離子液體中進行Cyclization。
Cyclopropanation
Rhodium Acetate Dimer Immobilized in 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid:a Novel and Recyclable Catalytic System for the Cyclopropanation of AlkenesAdv. Synth. Catal.2004, 346, 53. 以離子液體與Rhodium Acetate混合做為催化與可回收溶劑進行Cyclopropanation。
Debromination & Microwave
Catalysis by Ionic Liquid. A Green Protocol for the Stereoselective Debromination of vicinal-Dibromides by [pmIm]BF4 under Microwave IrradiationJ. Org. Chem. 2005, 70, 8621. 離子液體搭配微波進行debromination不需要金屬或還原劑催化。
Diels-Alder Reaction
Converting exo-Selective Diels-Alder Reaction to endo-Selective in Chloroloaluminate Ionic LiquidsJ. Org. Chem.2004, 69, 1419. 以離子液體改變Diels-Alder reaction的exo/endo選擇性。
High Regioselective Diels-Alder Reaction of Myrcene with Acrolein Catalyzed by Zinc-Containing Ionic LiquidsAdv. Synth. Catal. 2005, 347, 266. 在離子液體中以Zn催化Diels-Alder Reaction。
Dihydroxylation
OsO4 in Ionic Liquid [Bmim]PF6: A Recyclable and Reusable Catalyst System for Olefin Dihydroxylation. Remarkable Effect of DMAPOrg. Lett. 2002, 4, 2197. 以離子液體增加OsO4的回收與穩定性。
Elimination
Effect of Ionic Liquid Organizing Ability and Amine Structure on the Rate and Mechanism of Base Induced Elimination of 1,1,1-tribromo-2,2-bis(phenyl-substituted)ethanesTetrahedron 2006, 62, 1690. 在離子液體中進行鹼催化之消去反應。
Fischer esterification
Novel Bronsted Acidic Ionic Liquids and Their Use as Dual Solvent-CatalystsJ. Am. Chem. Soc.2002, 124, 5962. 離子液體同時作為酯化反應酸催化劑與溶劑。
Bronsted Acidic Ionic Liquids: A Green, Efficient and Reusable Catalyst System and Reaction Medium for Fischer EsterificationJournal of Molecular Catalysis A: Chemical 2005, 234, 107. 以Bronsted acidic離子液體進行Fischer esterification。
Friedel-Crafts Alkylation
Activity and Stability Investigation of [BMIM][AlCl4] Ionic Liquid as Catalyst for Alkylation of Benzene with 1-dodeceneApplied Catalysis A: General2004, 276 , 61 以含AlCl3的離子液體進行Friedel-Crafts Alkylation。
Dramatic Enhancement of Catalytic Activity in an Ionic Liquid: Highly Practical Friedel–crafts Alkenylation of Arenes with Alkynes Catalyzed by Metal TriflatesAngew. Chem.2004, 116, 6309. 以離子液體與Metal Triflates改善Friedel–Crafts Alkenylation。
Friedel–crafts Alkylation Reactions in Pyridinium-based Ionic LiquidsJournal of Molecular Catalysis A: Chemical 2005, 230, 129. 以pyridinium離子液體進行Friedel-Crafts Alkylation。
Alkylation of a-methylnaphthalene with Long-chain Alkenes Catalyzed by Butylpyridinium Bromochloroaluminate Ionic LiquidsJournal of Molecular Catalysis A: Chemical 2005, 231, 137. 以pyridinium離子液體將a-methylnaphthalene進行Friedel-Crafts Alkenylation。
Friedel-crafts Acylation
Friedel-crafts Acylation of Aromatics Catalysed by Supported Ionic LiquidsApplied Catalysis A: General 2001, 215, 185. 以含FeCl3的離子液體進行Friedel-Crafts Acylation。
Activation of Bismuth(III) Derivatives in Ionic Liquids: Novel and Recyclable Catalytic Systems for Friedel-crafts Acylation of Aromatic CompoundsOrg. Lett. 2003, 5, 2219.以離子液體與Bi(III)衍生物混合做為催化與可回收溶劑。
Friedel-crafts Acylation Reactions in Pyridinium Based Ionic LiquidsJ. Organomet. Chem.2005, 690, 3609. 以pyridinium離子液體進行Friedel-Crafts Acylation。
Friedel-crafts Phosphylation
Friedel-crafts Phosphylation of Benzene Catalyzed by [trEHAm]Cl-XAlCl3 Ionic LiquidsApplied Catalysis A: General 2004, 262, 101.以含AlCl3的離子液體進行Friedel-Crafts phosphylation。
Friedel-crafts Reaction
Highly Selective Synthesis of Diphenylmethane with Acidic Ionic LiquidsInd. Eng. Chem. Res. 2006, 45, 1571. 以離子液體改善Diphenylmethane的合成。
Friedel-crafts Sulfonylation
Friedel-crafts Sulfonylation in 1-Butyl-3-methylimidazolium Chloroaluminate Ionic LiquidsJ. Org. Chem. 2001, 66, 8616. Friedel-crafts Sulfonylation在離子液體中的應用。
Sulfonylation Reactions of Aromatics Using FeCl3-based Ionic LiquidsJournal of Molecular Catalysis A: Chemical 2004, 223, 75. 以含FeCl3的離子液體進行Friedel-Crafts Sulfonylation。
Grignard Reaction
An Iron-Containing Ionic Liquid as Recyclable Catalyst for Aryl Grignard Cross-Coupling of Alkyl HalidesOrg. Lett. 2006, 8, 733. 以含鐵之離子液體催化進行Grignard Reaction。
Halogenation
Stereoselective Halogenations of Alkenes and Alkynes in Ionic LiquidsOrg. Lett. 2001, 3, 1061. 以離子液體加速electrophilicaddition避免產生副產物達到高立體選擇性。
Efficient Halogenation of Aromatic Systems Using N-Halosuccinimides in Ionic LiquidsAdv. Synth. Catal.2004, 346, 77. 在離子液體中以N-Halosuccinimides進行Halogenation。
Heck Reaction & Microwave
High-Speed Heck Reactions in Ionic Liquid with Controlled Microwave HeatingJ. Org. Chem. 2002, 67, 6243. 以離子液體搭配微波加速Heck reaction。
Heck Reaction
Solvents from Biorenewable Sources: Ionic Liquids Based on FructoseOrg. Lett. 2003, 5, 2513. 新的Fructose衍生之離子液體進行Heck Reaction成果也不輸給傳統的[bmim]系列。
Copper Bronze Catalyzed Heck Reaction in Ionic Liquids Org. Lett. 2005, 7, 617. 以離子液體及銅奈米粒子催化Heck Reaction。
Bronsted Guanidine Acid-Base Ionic Liquids: Novel Reaction Media for the Palladium Catalyzed Heck ReactionOrg. Lett. 2006, 8,391. 以Guanidine離子液體進行Heck Reaction。
Heck Reaction & Suzuki Coupling
Highly Efficient, Recyclable Catalyst for C-C Coupling Reactions in Ionic Liquids: Pyrazolyl-Functionalized N-Heterocyclic Carbene Complex of Palladium(II)J. Org. Chem. 2006, 71, 426. 離子液體可以與palladium形成穩定的N-heterocyclic carbine complex同時作為可回收的溶劑與催化劑。
Hetero-Diels-Alder
High-Speed Microwave-Promoted Hetero-Diels-Alder Reactions of 2(1H)-Pyrazinones in Ionic Liquid Doped SolventsJ. Org. Chem. 2002, 67, 7904. 微波時加入少量的離子液體比起易揮發溶劑更適合瞬間加熱。
Hydrogenation
Asymmetric Hydrogenation and Catalyst Recycling Using Ionic Liquid and Supercritical Carbon DioxideJ. Am. Chem. Soc. 2001, 123, 1254. 以超臨界流體萃取離子液體中氫化的產物。
Transition-Metal Nanoparticles in Imidazolium Ionic Liquids: Recycable Catalysts for Biphasic Hydrogenation ReactionsJ. Am. Chem. Soc. 2002, 124, 4228. 離子液體可以作為穩定過渡金屬即可回收之兩相氫化溶劑。
Alternative Synthesis of a Dialkylimidazolium Tetrafluoroborate Ionic Liquid Mixture and its Use in Poly(acrylonitrile-butadiene) HydrogenationAdv. Synth. Catal.2002, 344, 153.合成便宜的離子液體混合物用於氫化。
A Comparison of Ruthenium-catalysed Arene Hydrogenation Reactions in Water and 1-Alkyl-3-methylimidazolium Tetrafluoroborate Ionic LiquidsAdv. Synth. Catal.2003, 345, 216. 在離子液體中以Ru催化Arene Hydrogenation。
Hydrogenation of Low Molecular Weight Polymers in Ionic Liquids and the Effects of Added SaltAdv. Synth. Catal.2003, 345, 568. 在離子液體中氫化Low Molecular Weight Polymers。
Enantioselective Hydrogenation of Trimethylindolenine in Ionic LiquidsAdv. Synth. Catal.2004, 346, 989. 在離子液體中以催化Ir-XYLIPHOS進行enantioselective hydrogenation。
Selective Hydrogenation of 1,3-Butadiene to 1-Butene by Pd(0) Nanoparticles Embedded in Imidazolium Ionic LiquidsAdv. Synth. Catal.2005, 347, 1404. 在離子液體中以Pd奈米粒子催化氫化反應。
Ionic Liquids in Regioselective Platinum-catalysed HydroformylationJournal of Molecular Catalysis A: Chemical 2000, 164, 61. 在離子液體中以Pt催化Hydroformylation。
Catalyzing Henry Reactions in Chloroaluminate Ionic Liquids在離子液體中進行Henry Reaction。
Isomerization Reaction & Claisen Rearrangement & Diels-Alder Reaction
Using Geminal Dicationic Ionic Liquids as Solvents for High-Temperature Organic ReactionsOrg. Lett. 2005, 7, 4205.以雙陽離子離子液體進行高溫有機反應。
Inorganic Synthesis
Interfacial Synthesis of Hollow TiO2 Microspheres in Ionic LiquidsJ. Am. Chem. Soc.2003, 125, 6386. 離子液體合成TiO2顆粒。
Synthesis of Very Small TiO2 Nanocrystals in a Room-Temperature Ionic Liquid and Their Self-Assembly toward Mesoporous Spherical AggregatesJ. Am. Chem. Soc.2003, 125, 14960. 離子液體合成TiO2奈米結晶。
Synthesis of CoPt Nanorods in Ionic LiquidsJ. Am. Chem. Soc. 2005, 127, 5316.離子液體中合成CoPt奈米棒。
Knoevenagel Condensation & Robinson Annulation
Base-promoted Reactions in Ionic Liquid Solvents. The Knoevenagel and Robinson Annulation ReactionsTetrahedron Lett.2001, 42, 6053. 在鹼性條件下已離子液體進行Knoevenagel condensation & Robinson annulation。
Michael Addition
Catalysis by Ionic Liquid: A Simple, Green and Efficient Procedure for the Michael Addition of Thiols and Thiophosphate to Conjugated Alkenes in Ionic Liquid, [pmIm]BrTetrahedron 2004, 60, 4183. 以離子液體進行Michael Addition,將thiol及thiophosphate與conjugated alkene反應。
Ionic Liquid as Catalyst and Reaction Medium. The Dramatic Influence of a Task-Specific Ionic Liquid, [bmIm]OH, in Michael Addition of Active Methylene Compounds to Conjugated Ketones, Carboxylic Esters, and NitrilesOrg. Lett. 2005, 7,3049. 以[bmIm][OH]這種特用性離子液體進行Michael Addition。
Nucleophilic Substitution & Microwave
Sensible Improvements Induced by Ionic Liquids in the Reaction of Modified Carbasugars with Bases for the Building of Constrained CarbanucleosidesJ. Org. Chem. 2004, 69, 2881. 以離子液體搭配微波改善Carbanucleosides的合成效率。
Oxidation
Room Temperature Liquid Salts of Cr and Mo as Self-Supported OxidantsAdv. Synth. Catal.2005, 347, 231. 將chlorochromate或molybdate作為離子液體的陰離子形成Self-Supported Oxidants。
Oxybromination
Oxybromination of Ethynylbenzene Catalysed by Molybdenum Complexes in Organic Solvent and in Ionic LiquidsAdv. Synth. Catal.2005, 347, 1341. 比較離子液體與傳統溶液以Mo催化Oxybromination的差別。
Pechmann Reaction
Pechmann Reaction in Non-Chloroaluminate Acidic Ionic Liquids under Solvent-Free ConditionsAdv. Synth. Catal.2005, 347, 512. 以Non-Chloroaluminate Acidic離子液體進行Pechmann condensation。
Pictet-Spengler Reaction & Microwave
Microwave accelerated Pictet–Spengler reactions of tryptophan with ketones directed toward the preparation of 1,1-disubstituted indole alkaloidsTetrahedron 2004, 60, 12075. 以離子液體與微波進行Pictet–Spengler reaction
Reorganization
Skeletal Reorganization of Enynes into 1-Vinylcycloalkenes in Ionic LiquidsJ. Org. Chem.2004, 69, 8541. 溶劑改成離子液體時可以以更溫和的調件進行反應。
Ring-closing metathesis
An Ionic Liquid-Supported Ruthenium Carbene Complex: A Robust and Recyclable Catalyst for Ring-Closing Olefin Metathesis in Ionic LiquidsJ. Am. Chem. Soc. 2003, 125, 9248. 將Grubbs’s試劑修飾在離子液體上,方便回收再利用。
Rosenmund-von Braun Reaction
Catalytic Rosenmund–von Braun Reaction in Halide-based Ionic LiquidsTetrahedron Lett.2002, 43, 387. 在離子液體中進行Rosenmund-von Braun Reaction
Silylation
Preparation of Silyl Enol Ethers Using (Bistrimethylsilyl)acetamide in Ionic LiquidsOrg. Lett. 2001, 3, 1037.使用離子液體可以減少原本有毒物質的使用。
Silylstannation
Recyclable Palladium(0)-catalysed Silylstannation of Terminal Alkynes in Ionic LiquidsJournal of Molecular Catalysis A: Chemical 2004, 214, 33. 在離子液體中進行Pt催化之silylstannation。
Sonogashira Coupling
Efficient Synthesis of Tribenzohexadehydro[12]annulene and Its Derivatives in the Ionic LiquidJ. Org. Chem. 2005, 70, 3285. 在離子液體中反應可以抑制homocoupling。
Stetter Reaction
Stetter Reaction in Room Temperature Ionic Liquids and Application to the Synthesis of HaloperidolAdv. Synth. Catal.2004, 346, 1329. 在離子液體中進行Stetter Reaction。
Stille Coupling
Organic Synthesis in Ionic Liquids: The Stille CouplingOrg. Lett. 2001, 3, 233. 在離子液體中進行Stille Coupling。
Suzuki Coupling
Exploration of Ionic Liquids as Soluble Supports for Organic Synthesis. Demonstration with a Suzuki Coupling ReactionOrg. Lett. 2003, 5, 5003. 在離子液體中進行Suzuki Coupling。
N-donor Complexes of Palladium as Catalysts for Suzuki Cross-coupling Reactions in Ionic LiquidsJournal of Molecular Catalysis A: Chemical 2004, 214, 27. 以N-donor的Pt錯合物為催化劑在離子液體中進行Suzuki Coupling。
Synthesis of a-Hydroxylamino Phosphonates
Three-Component One-Pot Synthesis of a-Hydroxylamino Phosphonates using Ionic Liquids Adv. Synth. Catal.2003, 345, 564. 在離子液體中合成a-Hydroxylamino Phosphonates。
Synthesis of Bis(1H-indol-3-yl)methanes
Efficient and Eco-Friendly Process for the Synthesis of Bis(1H-indol-3-yl)methanes using Ionic LiquidsAdv. Synth. Catal.2003, 345, 349. 在離子液體中合成Bis(1H-indol-3-yl)methanes。
Synthesis of Tetrahydro-b-carbolinediketopiperazines & Microwave
Synthesis of Tetrahydro-b-carbolinediketopiperazines in [bdmim][PF6 ] Ionic Liquid Accelerated by Controlled Microwave HeatingTetrahedronLett.2004, 45, 8137. 利用離子液體為溶劑與微波加熱合成Tetrahydro-b-carbolinediketopiperazines。
synthesis of Tetrahydro-b-carbolinequinoxalinone
Synthesis of Fused Tetrahydro-b-carbolinequinoxalinones in 1-n -butyl-2,3-Dimethylimidazolium Bis(trifluoromethylsulfonyl) Imide ([bdmim][Tf2 N]) and 1-n -butyl-2,3-Dimethylimidazolium Perfluorobutylsulfonate ([bdmim][PFBuSO3 ]) Ionic LiquidsTetrahedronLett.2005, 46, 6131.利用離子液體為溶劑合成Tetrahydro-b-carbolinequinoxalinone。
Synthesis of Thioethers,Thioesters and Dithianes
Ionic Liquid as Catalyst and Reaction Medium: A Simple, Convenient and GreenProcedure for the Synthesis of Thioethers, Thioesters and Dithianes using an Inexpensive Ionic Liquid, [pmIm]Br Adv. Synth. Catal.2005, 347, 1811. 以離子液體為催化劑與反應介質合成Thioethers, Thioesters and Dithianes。
Synthesis of vic-Diamines
1-Butyl-3-methylimidazolium Tetrafluoroborate ([Bmim]BF4) Ionic Liquid:A Novel and Recyclable Reaction Medium for the Synthesis of vic-DiaminesAdv. Synth. Catal.2003, 345, 948. 在離子液體中合成vic-Diamines。
Thioacetaliztion
Investigations Towards the Chemoselective Thioacetaliztion of Carbonyl Compounds by Using Ionic Liquid [bmim]Br as a Recyclable Catalytic MediumAdv. Synth. Catal. 2004, 346, 579. 在離子液體中進行Chemoselective Thioacetaliztion。
微波輔助合成離子液體
An Improved Preparation of 1,3-dialkylimidazolium Tetrafluoroborate Ionic Liquids using Microwaves.Tetrahedron Letters, 2002, 43(31), 5381-5383.
Microwave-Assisted Synthesis of Room-Temperature Ionic Liquid Precursor in Closed Vessel.Organic Process Research & Development, 2002, 6(6), 826-828.
Improved Preparations of Ionic Liquids using Microwave Irradiation.Green Chemistry, 2003, 5(2), 181-186.
Analytical Chemistry

Separations

Nonmolecular Solvents in Separation Methods: Dual Nature of Room Temperature Ionic Liquids Anal. Chem. 2005, 77, 4701.

Capillary electrophoresis

Application of 1-alkyl-3-methylimidazolium-based Ionic Liquids in Non-aqueous Capillary Electrophoresis J. of Chromatography A 2002, 979, 27.

Ionic Liquids in Chromatography and Capillary Electrophoresis J. of liquid chromatography & related technologies, 2004, 27, 1443.

Extraction

Nafion Membrane-supported Ionic Liquid - Solid Phase Microextraction for Analyzing Ultra Trace PAHs in Water Samples Anal. Chim. Acta 2006, 557, 321.

Room Temperature Ionic Liquids as Novel Media for 'clean' Liquid - Liquid Extraction — Chemical Communications (Cambridge), 1998(16), 1765-1766.
Opportunities for Ionic liquids in Recovery of Biofuels.— Chemical Communications (Cambridge), 2001(3), 295-296.
Dynamically Coating the Capillary with 1-alkyl-3-methylimidazolium-based Ionic Liquids for Separation of Basic Proteins by Capillary ElectrophoresisAnalytica Chimica Acta, 2003. 479(2), 249-254
Green processing using ionic liquids and CO2 — Nature (London), 1999. 399(6731), 28-29.
Task-Specific Ionic Liquids Incorporating Novel Cations for the Coordination and Extraction of Hg2+ and Cd2+: Synthesis, Characterization, and Extraction StudiesEnvironmental Science and Technology, 2002. 36(11), 2523-2529
Traditional Extractants in Nontraditional Solvents: Groups 1 and 2 Extraction by Crown Ethers in Room-Temperature Ionic LiquidsIndustrial & Engineering Chemistry Research, 2000. 39(10), 3596-3604.
Liquid/liquid Extraction of Metal Ions in Room Temperature Ionic Liquids Separation Science and Technology, 2001. 36(5 & 6), 785-804.
Room Temperature Ionic Liquid as a Novel Medium for Liquid/liquid Extraction of Metal Ions.— Analytica Chimica Acta, 2003. 488(2), 183-192.

pH-Dependent Partitioning in Room Temperature Ionic Liquids Provides a Link to Traditional Solvent Extraction BehaviorGreen Chem., 2000, 1, 1. Ionic liquid are being investigated as “green chemistry” replacements for volatile compounds (VOCs) which are traditionally used as solvent.

Environmentally Safe Ionic Liquids for Chiral Resolution — Japan Patent JP 2004277351, 2004

GC

High Stability Ionic Liquids. A New Class of Stationary Phases for Gas Chromatography Anal. Chem. 2003, 75, 4851.

Examination of Ionic Liquids and Their Interaction with Molecules, When Used as Stationary Phases in Gas Chromatography.Analytical Chemistry, 1999, 71(17), 3873-3876.

Ionic Liquids as Advantageous Solvents for Headspace Gas Chromatography of Compounds with Low Vapor Pressure Anal. Chem. 2005, 77, 702.

Characterizing Ionic Liquids On the Basis of Multiple Solvation InteractionsJournal of the American Chemical Society, 2002,124(47), 14247-14254.
High-stability Ionic Liquids. A New Class of Stationary Phases for Gas ChromatographyAnalytical Chemistry, 2003, 75(18), 4851-4858.
LC
Effect of 1-alkyl-3-methylimidazolium-based Ionic Liquids as the Eluent on the Separation of Ephedrines by Liquid ChromatographyJournal of Chromatography, A 2003, 1007(1-2), 39-45.

N-methylimidizolium Anion-exhange Stationary Phase for High-performance Liquid Chromatography J. Chromatography A 2006, 1103, 265.

Suppression of Deleterious Effects of Free Silanols in Liquid Chromatography by Imidazolium Tetrafluoroborate Ionic Liquids.Journal of Chromatography, A 2004, 1030(1-2), 263-271.
Ionic Liquids as Additives in High Performance Liquid Chromatography. Analysis of Amines and the Interaction Mechanism of Ionic Liquids.Analytica Chimica Acta, 2004, 519(2), 207-211.

Mass Spectrometry.

Matrix-assisted Laser Desorption/Ionization Mass Spectrometric Analysis of Uncomplexed Highly Sulfated Oligosaccharides Using Ionic Liquid Matrices Anal. Chem.2006, 78(6), 1774.

Aflatoxin Screening by MALDI-TOF Mass Spectrometry Anal. Chem. 2006, 77(24), 8155.

Pyridinium-based Ionic Liquid Matrices can Improve the Identification of Proteins by Peptide Mass-fingerprint Analysis with Matrix-assisted Laser Desorption/Ionization Mass Spectrometry Anal. And Bioanal. Chem. 2006, 384, 215.

Quantification of Peptides for the Monitoring of Protease-catalyzed Reactions by Matrix-assisted Laser Desorption/Ionization Mass Spectrometry using Ionic Liquid Matrixes Anal. Chem.2006, 78, 291.

Ionic-liquid Matrices for Quantitative Analysis by MALDI-TOF Mass Spectrometry Journal of American Society for Mass spectrometry2004, 15, 1833.

Ionic-liquids as Matrixes for Matrix-assisted Laser Desorption/Ionization Mass Spectrometry Anal. Chem.2001, 73, 3679.

Solvent for spectroscopy

Room-temperature Ionic Liquid as Solvents for Electronic Absorption Spectroscopy of Halide complexesNature, 1986, 323, 614

Screening of an Ionic Liquid as Medium for Photochemical Reactions — Chem. Phys. Lett.,2002, 362, 435. The IL [BMIM][PF6] has been used as solvent for a series of representative photochemical reactions.

Others

Ultra-deep Desulfurization of Transportation Fuels via Charge-transfer Complexes under Ambient Conditions Green Chem. 2005, 7, 413.

Wide Electrochemical Window at the Interface Between Water and a Hydrophobic Room-Temperature Ionic Liquid of Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate Anal. Chem. 2006, 78, 2726

Self-assembly of Block Copolymer Micelles in an Ionic Liquid  J. Am. Chem. Soc. 2006, 128(8): 2745.

Dye-sensitized Solar Cells Fabricated by Electrospray Coating using TiO2 Nanocrystal Dispersion Solution J. Electrochem. Soc. 2006, 153 (5), A826.

Charge Separation and Efficient Light Energy Conversion in Sensitized Mesoscopic Solar Cells Based on Binary Ionic Liquids  J. Am. Chem. Soc. 2005, 127 (18): 6850.

Fabrication and Surface Functionalization of Nanoporous Gold by Electrochemical Alloying/Dealloying of Au-Zn in an Ionic Liquid, and the Self-assembly of L-cysteine Monolayers Advanced Functional Materials 2005, 15 (6): 989.

CO2 Capture by a Task-specific Ionic Liquid  J. Am. Chem. Soc. 2003, 124 (6): 926-927 FEB 13 2003.

Toxicity

On the Freshwater Ecotoxicity and Biodegradation Properties of Some
Common Ionic Liquids - Organic Process Research and Development 2006, 10,
794.
— It is suggsted that ionic liquids can be ecotoxic. Contamination of aqueous effluent streams by these materials should be avoided.

 
Taiwanese researchers' papers
國立中正大學化學暨生物化學系, 朱延和Tetrahedron Letters 2006, 47 1575.
國立中正大學化學暨生物化學系, 魏國佐J. Am. Chem. Soc. 2004, 126(16), 5036.
國立成功大學大學化學系, 孫亦文 Tetrahedron 2005, 61 4857.
   
 
 
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