| Synthesis and Catalysis |
[3+2] Cycloaddition |
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Rate Accelerations of 1,3-dipolar Cycloaddition Reactions in Ionic Liquids — Tetrahedron Lett.2000, 41, 735. 在離子液體中進行[3+2] Cycloaddition。 |
| [4+2] Cycloaddition |
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[4+2] Cycloaddition of Ortho-quinone Methides Promoted by Ionic Liquids: an Efficient and Mild Protocol for the Synthesis of Tetrahydropyranobenzopyrans — Adv. Synth. Catal. 2004, 346, 607. 在離子液體中進行[4+2] Cycloaddition合成Tetrahydropyranobenzopyrans。 |
| Acetalization |
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Application of Functional Ionic Liquids Possessing Two Adjacent Acid Sites for Acetalization of Aldehydes — J. Org. Chem. 2004, 69, 3582. 利用修飾過帶酸性的離子液體進行Acetalization。 |
| Aldol Reaction |
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Direct Catalytic Asymmetric Cross-aldol Reactions in Ionic Liquid Media — Tetrahedron Lett.2004, 45, 3949. 以proline在離子液體中催化不對稱Aldol Reaction。 |
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Supported Ionic Liquids. New Recyclable Materials for the L-Proline-Catalyzed Aldol Reaction — Adv. Synth. Catal. 2006, 348, 82.將離子液體修飾在silica gel上利用L-Proline催化Aldol Reaction。 |
| Asymmetric Aminohalogenation |
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Ionic Liquid Media Resulted in the First Asymmetric Aminohalogenation Reaction of Alkenes — Org. Lett. 2004, 6, 4881.這個例子中離子液體可以進行傳統溶劑沒反應的Asymmetric Aminohalogenation。 |
| Asymmetric Diels-Alder Reaction |
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Asymmetric Diels-Alder Reactions in Ionic Liquids — Tetrahedron Lett.2003, 44, 6465. 離子液體中的Asymmetric Diels-Alder Reaction。 |
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Recycling Chiral Imidazolidin-4-one Catalyst for Asymmetric Diels-alder Reactions: Screening of Various Ionic Liquids — Adv. Synth. Catal. 2004, 346, 49. 在離子液體中以imidazolidin-4-one催化Asymmetric Diels-Alder Reaction。 |
| Asymmetric Michael Addition |
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An Ionic Liquid Influenced L-proline Catalysed Asymmetric Michael Addition of Ketones to Nitrostyrene — Journal of Molecular Catalysis A: Chemical 2005, 235, 267. 在離子液體中加入L-proline催化Asymmetric Michael Addition。 |
| Aza-Michael Reaction |
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Cu(acac)2 Immobilized in Ionic Liquids: A Recoverable and Reusable Catalytic System for Aza-michael Reactions — Adv. Synth. Catal.2005, 347, 763. 在離子液體中以Cu催化Aza-Michael Reaction。 |
| Biocatalysis |
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Ionic Liquid-Coated Enzyme for Biocatalysis in Organic Solvent — J. Org. Chem. 2002, 67, 6845. 酵素在離子液體中可以回收重複使用活性不減。 |
| Baylis-Hillman Reaction |
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Baylis-hillman Reaction in [bdmim][PF6] Ionic Liquid — Tetrahedron Lett. 2004, 45, 4673. 在離子液體中進行Baylis-Hillman reaction。 |
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The DABCO-catalysed Baylis-hillman Reactions in the Chloroaluminate Room Temperature Ionic Liquids: Rate Promoting and Recyclable Media — Journal of Molecular Catalysis A: Chemical 2004, 211, 43. 以DABCO催化及含AlCl3之離子液體進行Baylis-Hillman reaction。 |
| Copper Catalyzed Cross-Coupling |
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Bipyridinium Ionic Liquid-Promoted Cross-Coupling Reactions between Perfluoroalkyl or Pentafluorophenyl Halides and Aryl Iodides — Org. Lett. 2005, 7, 1963. 以Bipyridinium離子液體進行銅催化Cross-Coupling。 |
| Claisen Condensation & Knoevenagel Condensation |
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Assessment of the Suitability of Imidazolium Ionic Liquids as Reaction Medium for Base-catalysed Reactions Case of Knoevenagel and Claisen–schmidt Reactions — Journal of Molecular Catalysis A: Chemical2004, 214, 137. 在離子液體中以鹼催化進行Claisen Condensation & Knoevenagel Condensation。 |
| Cyclization |
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A Novel Reaction in Ionic Liquids: Selective Cyclization of 1-dodecene to Cyclododecane Under Moderate Pressure — Tetrahedron Lett.2003, 44, 2191. 在離子液體中進行Cyclization。 |
| Cyclopropanation |
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Rhodium Acetate Dimer Immobilized in 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid:a Novel and Recyclable Catalytic System for the Cyclopropanation of Alkenes — Adv. Synth. Catal.2004, 346, 53. 以離子液體與Rhodium Acetate混合做為催化與可回收溶劑進行Cyclopropanation。 |
| Debromination & Microwave |
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Catalysis by Ionic Liquid. A Green Protocol for the Stereoselective Debromination of vicinal-Dibromides by [pmIm]BF4 under Microwave Irradiation — J. Org. Chem. 2005, 70, 8621. 離子液體搭配微波進行debromination不需要金屬或還原劑催化。 |
| Diels-Alder Reaction |
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Converting exo-Selective Diels-Alder Reaction to endo-Selective in Chloroloaluminate Ionic Liquids — J. Org. Chem.2004, 69, 1419. 以離子液體改變Diels-Alder reaction的exo/endo選擇性。 |
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High Regioselective Diels-Alder Reaction of Myrcene with Acrolein Catalyzed by Zinc-Containing Ionic Liquids — Adv. Synth. Catal. 2005, 347, 266. 在離子液體中以Zn催化Diels-Alder Reaction。 |
| Dihydroxylation |
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OsO4 in Ionic Liquid [Bmim]PF6: A Recyclable and Reusable Catalyst System for Olefin Dihydroxylation. Remarkable Effect of DMAP — Org. Lett. 2002, 4, 2197. 以離子液體增加OsO4的回收與穩定性。 |
| Elimination |
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Effect of Ionic Liquid Organizing Ability and Amine Structure on the Rate and Mechanism of Base Induced Elimination of 1,1,1-tribromo-2,2-bis(phenyl-substituted)ethanes — Tetrahedron 2006, 62, 1690. 在離子液體中進行鹼催化之消去反應。 |
| Fischer esterification |
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Novel Bronsted Acidic Ionic Liquids and Their Use as Dual Solvent-Catalysts — J. Am. Chem. Soc.2002, 124, 5962. 離子液體同時作為酯化反應酸催化劑與溶劑。 |
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Bronsted Acidic Ionic Liquids: A Green, Efficient and Reusable Catalyst System and Reaction Medium for Fischer Esterification — Journal of Molecular Catalysis A: Chemical 2005, 234, 107. 以Bronsted acidic離子液體進行Fischer esterification。 |
| Friedel-Crafts Alkylation |
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Activity and Stability Investigation of [BMIM][AlCl4] Ionic Liquid as Catalyst for Alkylation of Benzene with 1-dodecene — Applied Catalysis A: General2004, 276 , 61 以含AlCl3的離子液體進行Friedel-Crafts Alkylation。 |
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Dramatic Enhancement of Catalytic Activity in an Ionic Liquid: Highly Practical Friedel–crafts Alkenylation of Arenes with Alkynes Catalyzed by Metal Triflates — Angew. Chem.2004, 116, 6309. 以離子液體與Metal Triflates改善Friedel–Crafts Alkenylation。 |
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Friedel–crafts Alkylation Reactions in Pyridinium-based Ionic Liquids — Journal of Molecular Catalysis A: Chemical 2005, 230, 129. 以pyridinium離子液體進行Friedel-Crafts Alkylation。 |
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Alkylation of a-methylnaphthalene with Long-chain Alkenes Catalyzed by Butylpyridinium Bromochloroaluminate Ionic Liquids — Journal of Molecular Catalysis A: Chemical 2005, 231, 137. 以pyridinium離子液體將a-methylnaphthalene進行Friedel-Crafts Alkenylation。 |
| Friedel-crafts Acylation |
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Friedel-crafts Acylation of Aromatics Catalysed by Supported Ionic Liquids — Applied Catalysis A: General 2001, 215, 185. 以含FeCl3的離子液體進行Friedel-Crafts Acylation。 |
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Activation of Bismuth(III) Derivatives in Ionic Liquids: Novel and Recyclable Catalytic Systems for Friedel-crafts Acylation of Aromatic Compounds — Org. Lett. 2003, 5, 2219.以離子液體與Bi(III)衍生物混合做為催化與可回收溶劑。 |
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Friedel-crafts Acylation Reactions in Pyridinium Based Ionic Liquids — J. Organomet. Chem.2005, 690, 3609. 以pyridinium離子液體進行Friedel-Crafts Acylation。 |
| Friedel-crafts Phosphylation |
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Friedel-crafts Phosphylation of Benzene Catalyzed by [trEHAm]Cl-XAlCl3 Ionic Liquids — Applied Catalysis A: General 2004, 262, 101.以含AlCl3的離子液體進行Friedel-Crafts phosphylation。 |
| Friedel-crafts Reaction |
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Highly Selective Synthesis of Diphenylmethane with Acidic Ionic Liquids — Ind. Eng. Chem. Res. 2006, 45, 1571. 以離子液體改善Diphenylmethane的合成。 |
| Friedel-crafts Sulfonylation |
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Friedel-crafts Sulfonylation in 1-Butyl-3-methylimidazolium Chloroaluminate Ionic Liquids — J. Org. Chem. 2001, 66, 8616. Friedel-crafts Sulfonylation在離子液體中的應用。 |
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Sulfonylation Reactions of Aromatics Using FeCl3-based Ionic Liquids — Journal of Molecular Catalysis A: Chemical 2004, 223, 75. 以含FeCl3的離子液體進行Friedel-Crafts Sulfonylation。 |
| Grignard Reaction |
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An Iron-Containing Ionic Liquid as Recyclable Catalyst for Aryl Grignard Cross-Coupling of Alkyl Halides — Org. Lett. 2006, 8, 733. 以含鐵之離子液體催化進行Grignard Reaction。 |
| Halogenation |
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Stereoselective Halogenations of Alkenes and Alkynes in Ionic Liquids — Org. Lett. 2001, 3, 1061. 以離子液體加速electrophilicaddition避免產生副產物達到高立體選擇性。 |
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Efficient Halogenation of Aromatic Systems Using N-Halosuccinimides in Ionic Liquids — Adv. Synth. Catal.2004, 346, 77. 在離子液體中以N-Halosuccinimides進行Halogenation。 |
| Heck Reaction & Microwave |
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High-Speed Heck Reactions in Ionic Liquid with Controlled Microwave Heating — J. Org. Chem. 2002, 67, 6243. 以離子液體搭配微波加速Heck reaction。 |
| Heck Reaction |
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Solvents from Biorenewable Sources: Ionic Liquids Based on Fructose — Org. Lett. 2003, 5, 2513. 新的Fructose衍生之離子液體進行Heck Reaction成果也不輸給傳統的[bmim]系列。 |
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Copper Bronze Catalyzed Heck Reaction in Ionic Liquids — Org. Lett. 2005, 7, 617. 以離子液體及銅奈米粒子催化Heck Reaction。 |
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Bronsted Guanidine Acid-Base Ionic Liquids: Novel Reaction Media for the Palladium Catalyzed Heck Reaction — Org. Lett. 2006, 8,391. 以Guanidine離子液體進行Heck Reaction。 |
| Heck Reaction & Suzuki Coupling |
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Highly Efficient, Recyclable Catalyst for C-C Coupling Reactions in Ionic Liquids: Pyrazolyl-Functionalized N-Heterocyclic Carbene Complex of Palladium(II) — J. Org. Chem. 2006, 71, 426. 離子液體可以與palladium形成穩定的N-heterocyclic carbine complex同時作為可回收的溶劑與催化劑。 |
| Hetero-Diels-Alder |
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High-Speed Microwave-Promoted Hetero-Diels-Alder Reactions of 2(1H)-Pyrazinones in Ionic Liquid Doped Solvents — J. Org. Chem. 2002, 67, 7904. 微波時加入少量的離子液體比起易揮發溶劑更適合瞬間加熱。 |
| Hydrogenation |
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Asymmetric Hydrogenation and Catalyst Recycling Using Ionic Liquid and Supercritical Carbon Dioxide — J. Am. Chem. Soc. 2001, 123, 1254. 以超臨界流體萃取離子液體中氫化的產物。 |
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Transition-Metal Nanoparticles in Imidazolium Ionic Liquids: Recycable Catalysts for Biphasic Hydrogenation Reactions — J. Am. Chem. Soc. 2002, 124, 4228. 離子液體可以作為穩定過渡金屬即可回收之兩相氫化溶劑。 |
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Alternative Synthesis of a Dialkylimidazolium Tetrafluoroborate Ionic Liquid Mixture and its Use in Poly(acrylonitrile-butadiene) Hydrogenation — Adv. Synth. Catal.2002, 344, 153.合成便宜的離子液體混合物用於氫化。 |
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A Comparison of Ruthenium-catalysed Arene Hydrogenation Reactions in Water and 1-Alkyl-3-methylimidazolium Tetrafluoroborate Ionic Liquids — Adv. Synth. Catal.2003, 345, 216. 在離子液體中以Ru催化Arene Hydrogenation。 |
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Hydrogenation of Low Molecular Weight Polymers in Ionic Liquids and the Effects of Added Salt — Adv. Synth. Catal.2003, 345, 568. 在離子液體中氫化Low Molecular Weight Polymers。 |
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Enantioselective Hydrogenation of Trimethylindolenine in Ionic Liquids — Adv. Synth. Catal.2004, 346, 989. 在離子液體中以催化Ir-XYLIPHOS進行enantioselective hydrogenation。 |
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Selective Hydrogenation of 1,3-Butadiene to 1-Butene by Pd(0) Nanoparticles Embedded in Imidazolium Ionic Liquids — Adv. Synth. Catal.2005, 347, 1404. 在離子液體中以Pd奈米粒子催化氫化反應。 |
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Ionic Liquids in Regioselective Platinum-catalysed Hydroformylation — Journal of Molecular Catalysis A: Chemical 2000, 164, 61. 在離子液體中以Pt催化Hydroformylation。 |
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Catalyzing Henry Reactions in Chloroaluminate Ionic Liquids — 在離子液體中進行Henry Reaction。 |
| Isomerization Reaction & Claisen Rearrangement & Diels-Alder Reaction |
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Using Geminal Dicationic Ionic Liquids as Solvents for High-Temperature Organic Reactions — Org. Lett. 2005, 7, 4205.以雙陽離子離子液體進行高溫有機反應。 |
| Inorganic Synthesis |
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Interfacial Synthesis of Hollow TiO2 Microspheres in Ionic Liquids — J. Am. Chem. Soc.2003, 125, 6386. 離子液體合成TiO2顆粒。 |
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Synthesis of Very Small TiO2 Nanocrystals in a Room-Temperature Ionic Liquid and Their Self-Assembly toward Mesoporous Spherical Aggregates — J. Am. Chem. Soc.2003, 125, 14960. 離子液體合成TiO2奈米結晶。 |
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Synthesis of CoPt Nanorods in Ionic Liquids — J. Am. Chem. Soc. 2005, 127, 5316.離子液體中合成CoPt奈米棒。 |
| Knoevenagel Condensation & Robinson Annulation |
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Base-promoted Reactions in Ionic Liquid Solvents. The Knoevenagel and Robinson Annulation Reactions — Tetrahedron Lett.2001, 42, 6053. 在鹼性條件下已離子液體進行Knoevenagel condensation & Robinson annulation。 |
| Michael Addition |
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Catalysis by Ionic Liquid: A Simple, Green and Efficient Procedure for the Michael Addition of Thiols and Thiophosphate to Conjugated Alkenes in Ionic Liquid, [pmIm]Br — Tetrahedron 2004, 60, 4183. 以離子液體進行Michael Addition，將thiol及thiophosphate與conjugated alkene反應。 |
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Ionic Liquid as Catalyst and Reaction Medium. The Dramatic Influence of a Task-Specific Ionic Liquid, [bmIm]OH, in Michael Addition of Active Methylene Compounds to Conjugated Ketones, Carboxylic Esters, and Nitriles — Org. Lett. 2005, 7,3049. 以[bmIm][OH]這種特用性離子液體進行Michael Addition。 |
| Nucleophilic Substitution & Microwave |
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Sensible Improvements Induced by Ionic Liquids in the Reaction of Modified Carbasugars with Bases for the Building of Constrained Carbanucleosides — J. Org. Chem. 2004, 69, 2881. 以離子液體搭配微波改善Carbanucleosides的合成效率。 |
| Oxidation |
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Room Temperature Liquid Salts of Cr and Mo as Self-Supported Oxidants — Adv. Synth. Catal.2005, 347, 231. 將chlorochromate或molybdate作為離子液體的陰離子形成Self-Supported Oxidants。 |
| Oxybromination |
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Oxybromination of Ethynylbenzene Catalysed by Molybdenum Complexes in Organic Solvent and in Ionic Liquids — Adv. Synth. Catal.2005, 347, 1341. 比較離子液體與傳統溶液以Mo催化Oxybromination的差別。 |
| Pechmann Reaction |
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Pechmann Reaction in Non-Chloroaluminate Acidic Ionic Liquids under Solvent-Free Conditions — Adv. Synth. Catal.2005, 347, 512. 以Non-Chloroaluminate Acidic離子液體進行Pechmann condensation。 |
| Pictet-Spengler Reaction & Microwave |
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Microwave accelerated Pictet–Spengler reactions of tryptophan with ketones directed toward the preparation of 1,1-disubstituted indole alkaloids— Tetrahedron 2004, 60, 12075. 以離子液體與微波進行Pictet–Spengler reaction |
| Reorganization |
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Skeletal Reorganization of Enynes into 1-Vinylcycloalkenes in Ionic Liquids — J. Org. Chem.2004, 69, 8541. 溶劑改成離子液體時可以以更溫和的調件進行反應。 |
| Ring-closing metathesis |
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An Ionic Liquid-Supported Ruthenium Carbene Complex: A Robust and Recyclable Catalyst for Ring-Closing Olefin Metathesis in Ionic Liquids — J. Am. Chem. Soc. 2003, 125, 9248. 將Grubbs’s試劑修飾在離子液體上，方便回收再利用。 |
| Rosenmund-von Braun Reaction |
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Catalytic Rosenmund–von Braun Reaction in Halide-based Ionic Liquids — Tetrahedron Lett.2002, 43, 387. 在離子液體中進行Rosenmund-von Braun Reaction |
| Silylation |
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Preparation of Silyl Enol Ethers Using (Bistrimethylsilyl)acetamide in Ionic Liquids — Org. Lett. 2001, 3, 1037.使用離子液體可以減少原本有毒物質的使用。 |
| Silylstannation |
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Recyclable Palladium(0)-catalysed Silylstannation of Terminal Alkynes in Ionic Liquids — Journal of Molecular Catalysis A: Chemical 2004, 214, 33. 在離子液體中進行Pt催化之silylstannation。 |
| Sonogashira Coupling |
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Efficient Synthesis of Tribenzohexadehydro[12]annulene and Its Derivatives in the Ionic Liquid — J. Org. Chem. 2005, 70, 3285. 在離子液體中反應可以抑制homocoupling。 |
| Stetter Reaction |
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Stetter Reaction in Room Temperature Ionic Liquids and Application to the Synthesis of Haloperidol — Adv. Synth. Catal.2004, 346, 1329. 在離子液體中進行Stetter Reaction。 |
| Stille Coupling |
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Organic Synthesis in Ionic Liquids: The Stille Coupling — Org. Lett. 2001, 3, 233. 在離子液體中進行Stille Coupling。 |
| Suzuki Coupling |
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Exploration of Ionic Liquids as Soluble Supports for Organic Synthesis. Demonstration with a Suzuki Coupling Reaction — Org. Lett. 2003, 5, 5003. 在離子液體中進行Suzuki Coupling。 |
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N-donor Complexes of Palladium as Catalysts for Suzuki Cross-coupling Reactions in Ionic Liquids — Journal of Molecular Catalysis A: Chemical 2004, 214, 27. 以N-donor的Pt錯合物為催化劑在離子液體中進行Suzuki Coupling。 |
| Synthesis of a-Hydroxylamino Phosphonates |
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Three-Component One-Pot Synthesis of a-Hydroxylamino Phosphonates using Ionic Liquids — Adv. Synth. Catal.2003, 345, 564. 在離子液體中合成a-Hydroxylamino Phosphonates。 |
| Synthesis of Bis(1H-indol-3-yl)methanes |
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Efficient and Eco-Friendly Process for the Synthesis of Bis(1H-indol-3-yl)methanes using Ionic Liquids — Adv. Synth. Catal.2003, 345, 349. 在離子液體中合成Bis(1H-indol-3-yl)methanes。 |
| Synthesis of Tetrahydro-b-carbolinediketopiperazines & Microwave |
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Synthesis of Tetrahydro-b-carbolinediketopiperazines in [bdmim][PF6 ] Ionic Liquid Accelerated by Controlled Microwave Heating — TetrahedronLett.2004, 45, 8137. 利用離子液體為溶劑與微波加熱合成Tetrahydro-b-carbolinediketopiperazines。 |
| synthesis of Tetrahydro-b-carbolinequinoxalinone |
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Synthesis of Fused Tetrahydro-b-carbolinequinoxalinones in 1-n -butyl-2,3-Dimethylimidazolium Bis(trifluoromethylsulfonyl) Imide ([bdmim][Tf2 N]) and 1-n -butyl-2,3-Dimethylimidazolium Perfluorobutylsulfonate ([bdmim][PFBuSO3 ]) Ionic Liquids — TetrahedronLett.2005, 46, 6131.利用離子液體為溶劑合成Tetrahydro-b-carbolinequinoxalinone。 |
| Synthesis of Thioethers,Thioesters and Dithianes |
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Ionic Liquid as Catalyst and Reaction Medium: A Simple, Convenient and GreenProcedure for the Synthesis of Thioethers, Thioesters and Dithianes using an Inexpensive Ionic Liquid, [pmIm]Br — Adv. Synth. Catal.2005, 347, 1811. 以離子液體為催化劑與反應介質合成Thioethers, Thioesters and Dithianes。 |
| Synthesis of vic-Diamines |
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1-Butyl-3-methylimidazolium Tetrafluoroborate ([Bmim]BF4) Ionic Liquid:A Novel and Recyclable Reaction Medium for the Synthesis of vic-Diamines — Adv. Synth. Catal.2003, 345, 948. 在離子液體中合成vic-Diamines。 |
| Thioacetaliztion |
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Investigations Towards the Chemoselective Thioacetaliztion of Carbonyl Compounds by Using Ionic Liquid [bmim]Br as a Recyclable Catalytic Medium — Adv. Synth. Catal. 2004, 346, 579. 在離子液體中進行Chemoselective Thioacetaliztion。 |
| 微波輔助合成離子液體 |
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An Improved Preparation of 1,3-dialkylimidazolium Tetrafluoroborate Ionic Liquids using Microwaves. — Tetrahedron Letters, 2002, 43(31), 5381-5383. |
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Microwave-Assisted Synthesis of Room-Temperature Ionic Liquid Precursor in Closed Vessel. — Organic Process Research & Development, 2002, 6(6), 826-828. |
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Improved Preparations of Ionic Liquids using Microwave Irradiation. — Green Chemistry, 2003, 5(2), 181-186. |
| Analytical Chemistry |
Separations |
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Nonmolecular Solvents in Separation Methods: Dual Nature of Room Temperature Ionic Liquids — Anal. Chem. 2005, 77, 4701. |
Capillary electrophoresis |
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Application of 1-alkyl-3-methylimidazolium-based Ionic Liquids in Non-aqueous Capillary Electrophoresis — J. of Chromatography A 2002, 979, 27. |
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Ionic Liquids in Chromatography and Capillary Electrophoresis — J. of liquid chromatography & related technologies, 2004, 27, 1443. |
| Extraction |
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Nafion Membrane-supported Ionic Liquid - Solid Phase Microextraction for Analyzing Ultra Trace PAHs in Water Samples — Anal. Chim. Acta 2006, 557, 321. |
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Room Temperature Ionic Liquids as Novel Media for 'clean' Liquid - Liquid Extraction — Chemical Communications (Cambridge), 1998(16), 1765-1766. |
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Opportunities for Ionic liquids in Recovery of Biofuels.— Chemical Communications (Cambridge), 2001(3), 295-296. |
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Dynamically Coating the Capillary with 1-alkyl-3-methylimidazolium-based Ionic Liquids for Separation of Basic Proteins by Capillary Electrophoresis — Analytica Chimica Acta, 2003. 479(2), 249-254 |
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Green processing using ionic liquids and CO2 — Nature (London), 1999. 399(6731), 28-29. |
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Task-Specific Ionic Liquids Incorporating Novel Cations for the Coordination and Extraction of Hg2+ and Cd2+: Synthesis, Characterization, and Extraction Studies — Environmental Science and Technology, 2002. 36(11), 2523-2529 |
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Traditional Extractants in Nontraditional Solvents: Groups 1 and 2 Extraction by Crown Ethers in Room-Temperature Ionic Liquids — Industrial & Engineering Chemistry Research, 2000. 39(10), 3596-3604. |
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Liquid/liquid Extraction of Metal Ions in Room Temperature Ionic Liquids — Separation Science and Technology, 2001. 36(5 & 6), 785-804. |
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Room Temperature Ionic Liquid as a Novel Medium for Liquid/liquid Extraction of Metal Ions.— Analytica Chimica Acta, 2003. 488(2), 183-192. |
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pH-Dependent Partitioning in Room Temperature Ionic Liquids Provides a Link to Traditional Solvent Extraction Behavior — Green Chem., 2000, 1, 1. Ionic liquid are being investigated as “green chemistry” replacements for volatile compounds (VOCs) which are traditionally used as solvent. |
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Environmentally Safe Ionic Liquids for Chiral Resolution — Japan Patent JP 2004277351, 2004 |
| GC |
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High Stability Ionic Liquids. A New Class of Stationary Phases for Gas Chromatography — Anal. Chem. 2003, 75, 4851. |
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Examination of Ionic Liquids and Their Interaction with Molecules, When Used as Stationary Phases in Gas Chromatography. — Analytical Chemistry, 1999, 71(17), 3873-3876. |
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Ionic Liquids as Advantageous Solvents for Headspace Gas Chromatography of Compounds with Low Vapor Pressure — Anal. Chem. 2005, 77, 702. |
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Characterizing Ionic Liquids On the Basis of Multiple Solvation Interactions — Journal of the American Chemical Society, 2002,124(47), 14247-14254. |
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High-stability Ionic Liquids. A New Class of Stationary Phases for Gas Chromatography — Analytical Chemistry, 2003, 75(18), 4851-4858. |
| LC |
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Effect of 1-alkyl-3-methylimidazolium-based Ionic Liquids as the Eluent on the Separation of Ephedrines by Liquid Chromatography — Journal of Chromatography, A 2003, 1007(1-2), 39-45. |
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N-methylimidizolium Anion-exhange Stationary Phase for High-performance Liquid Chromatography — J. Chromatography A 2006, 1103, 265. |
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Suppression of Deleterious Effects of Free Silanols in Liquid Chromatography by Imidazolium Tetrafluoroborate Ionic Liquids. — Journal of Chromatography, A 2004, 1030(1-2), 263-271. |
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Ionic Liquids as Additives in High Performance Liquid Chromatography. Analysis of Amines and the Interaction Mechanism of Ionic Liquids. — Analytica Chimica Acta, 2004, 519(2), 207-211. |
Mass Spectrometry. |
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Matrix-assisted Laser Desorption/Ionization Mass Spectrometric Analysis of Uncomplexed Highly Sulfated Oligosaccharides Using Ionic Liquid Matrices — Anal. Chem.2006, 78(6), 1774. |
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Aflatoxin Screening by MALDI-TOF Mass Spectrometry — Anal. Chem. 2006, 77(24), 8155. |
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Pyridinium-based Ionic Liquid Matrices can Improve the Identification of Proteins by Peptide Mass-fingerprint Analysis with Matrix-assisted Laser Desorption/Ionization Mass Spectrometry — Anal. And Bioanal. Chem. 2006, 384, 215. |
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Quantification of Peptides for the Monitoring of Protease-catalyzed Reactions by Matrix-assisted Laser Desorption/Ionization Mass Spectrometry using Ionic Liquid Matrixes — Anal. Chem.2006, 78, 291. |
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Ionic-liquid Matrices for Quantitative Analysis by MALDI-TOF Mass Spectrometry — Journal of American Society for Mass spectrometry2004, 15, 1833. |
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Ionic-liquids as Matrixes for Matrix-assisted Laser Desorption/Ionization Mass Spectrometry — Anal. Chem.2001, 73, 3679. |
| Solvent for spectroscopy |
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Room-temperature Ionic Liquid as Solvents for Electronic Absorption Spectroscopy of Halide complexes — Nature, 1986, 323, 614 |
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Screening of an Ionic Liquid as Medium for Photochemical Reactions — Chem. Phys. Lett.,2002, 362, 435. The IL [BMIM][PF6] has been used as solvent for a series of representative photochemical reactions. |
Others |
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Ultra-deep Desulfurization of Transportation Fuels via Charge-transfer Complexes under Ambient Conditions — Green Chem. 2005, 7, 413. |
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Wide Electrochemical Window at the Interface Between Water and a Hydrophobic Room-Temperature Ionic Liquid of Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate — Anal. Chem. 2006, 78, 2726 |
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Self-assembly of Block Copolymer Micelles in an Ionic Liquid — J. Am. Chem. Soc. 2006, 128(8): 2745. |
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Dye-sensitized Solar Cells Fabricated by Electrospray Coating using TiO2 Nanocrystal Dispersion Solution — J. Electrochem. Soc. 2006, 153 (5), A826. |
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Charge Separation and Efficient Light Energy Conversion in Sensitized Mesoscopic Solar Cells Based on Binary Ionic Liquids — J. Am. Chem. Soc. 2005, 127 (18): 6850. |
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Fabrication and Surface Functionalization of Nanoporous Gold by Electrochemical Alloying/Dealloying of Au-Zn in an Ionic Liquid, and the Self-assembly of L-cysteine Monolayers — Advanced Functional Materials 2005, 15 (6): 989. |
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CO2 Capture by a Task-specific Ionic Liquid — J. Am. Chem. Soc. 2003, 124 (6): 926-927 FEB 13 2003. |
| Toxicity |
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On the Freshwater Ecotoxicity and Biodegradation Properties of Some
Common Ionic Liquids - Organic Process Research and Development 2006, 10,
794. — It is suggsted that ionic liquids can be ecotoxic. Contamination of aqueous effluent streams by these materials should be avoided.
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| Taiwanese researchers' papers |
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國立中正大學化學暨生物化學系, 朱延和 — Tetrahedron Letters 2006, 47 1575. |
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國立中正大學化學暨生物化學系, 魏國佐 — J. Am. Chem. Soc. 2004, 126(16), 5036. |
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國立成功大學大學化學系, 孫亦文 —Tetrahedron 2005, 61 4857. |
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